The unique features of X-ray absorption spectroscopy allow investigations of nanosized catalysts for fuel cells under working conditions. We present the results of an experiment carried out on a low Pt content electrocatalyst supported by a mesoporous heteropolyacid salt and used at the cathode of a proton exchange membrane fuel cell (PEMFC). The analysis of the EXAFS signal at the Pt L3-edge indicates that upon operating the fuel cell a substantial oxygen desorption from the Pt catalytic surface occurs followed by a tangible structural change on the Pt local order.
Authors
- Emiliano Principi,
- dr hab. inż. Agnieszka Witkowska link open in new tab ,
- Cicco Andrea Di
Additional information
- DOI
- Digital Object Identifier link open in new tab 10.1088/1742-6596/190/1/012173
- Category
- Aktywność konferencyjna
- Type
- publikacja w wydawnictwie zbiorowym recenzowanym (także w materiałach konferencyjnych)
- Language
- angielski
- Publication year
- 2009