The threshold photoelectron spectrum of the isoxazole molecule, C3H3NO has been measured over the photon energy range 9.9-30 eV with the use of synchrotron radiation. In the 9.9-10.8 eV range, corresponding to photoionization from the highest occupied molecular orbital 3a"(π3), seven well resolved vibrational series have been observed and their modes are tentatively assigned. A strong adiabatic ionization, with an energy of 11.132 ± 0.003 eV corresponding to the 2a"(π2) band, has also been observed. This is followed by a single vibrational series of the νC-H stretching mode. Photoelectron bands in the energy region 13-30 eV have also been identified, some for the first time.
Authors
- dr inż. Marcin Dampc link open in new tab ,
- dr Brygida Mielewska link open in new tab ,
- M.r.f. Siggel-King,
- George C. King,
- Bhakamurugan Sivaraman,
- Sylwia Ptasińska,
- N. J. Mason,
- prof. dr hab. inż. Mariusz Zubek link open in new tab
Additional information
- Category
- Publikacja w czasopiśmie
- Type
- artykuł w czasopiśmie wyróżnionym w JCR
- Language
- angielski
- Publication year
- 2010
