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Removal of sulfur from a solvent extract

The presence of sulfur in a solvent extract that is to be analyzed chromatographically impairs and sometimes precludes properinterpretation of the chromatogram, as the sulfur peak masks the peaks of other compounds present in the sample, and sulfur alsodisrupts the operation of the mass detector. This means that discrepancies in the results can lead to erroneous interpretations andfalse assessments of environmental risk. For this reason, sulfur should be removed from an extract prior to chromatographicanalysis and determined in a separate analytical run using an appropriate procedure.This article presents a critical analysis of known methods for removing elemental sulfur from solvent extracts prior to the finaldetermination step of chemicals in the group comprising polychlorinated biphenyls, polyaromatic hydrocarbons andpolybrominated diphenyl ethers.

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DOI
Digital Object Identifier link open in new tab 10.1016/j.trac.2011.06.022
Category
Publikacja w czasopiśmie
Type
artykuł w czasopiśmie wyróżnionym w JCR
Language
angielski
Publication year
2012

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