Thioamide derivatives of p-tert-butylcalix[4]arene were used as ionophores in the development of solid-contact ion-selective electrodes based on conducting polymer poly(3,4-ethylenedioxythiophene)/polystyrene sulfonate (PEDOT/PSS) which was synthesized by electrodeposition on the glassy carbon electrodes. The typical ion-selective membranes with optionally two different plasticizers [bis(2-ethylhexyl)sebacate (DOS) and 2-nitrophenyl octyl ether (NPOE)] were investigated. The potentiometric selectivity coefficients were determined by separate solution method (SSM) for Pb2+ over Cu2+, Cd2+ ,Ca2+, Na+, and K+. High selectivity toward Pb2+ was obtained. By applying twoconditioning protocols, a low detection limit log(aDL)≈−9 was achieved. The fabricated ion-selective electrodes were used to determine Pb2+ concentration in environmental samples. The obtained results were compared to analysis done by inductively coupled plasma mass spectrometry (ICPMS).
Authors
- mgr inż. Marcin Guziński link open in new tab ,
- Grzegorz Lisak,
- Tomasz Sokalski,
- Johan Bobacka,
- Ari Ivaska,
- Maria Bochenska,
- Andrzej Lewenstam
Additional information
- Category
- Publikacja w czasopiśmie
- Type
- artykuł w czasopiśmie wyróżnionym w JCR
- Language
- angielski
- Publication year
- 2013
