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Synthesis and application of tetrazole di and triamide derivatives in ion-selective membrane electrodes

A number of tetrazole diamides and triamides have been synthesized and applied as ion carries in ion-selective membrane electrodes. Their selectivity and sensitivity were studied towards alkali, alkaline earth, transition and heavy metal cations. it was found that membranes doped with 3 and 2-nitrophenyl octyl ether exhibit an almost theoretial Nernstian response for NH+ over relatively wide concentration range. Elestrodes with ionophores 4 and 5 with bis91-buthylpentyl) adipate show high affinity towards CD2+; another diamide with two plasticizers exhibits good selectivity fo Pb2+ ions.

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Additional information

Category
Publikacja w czasopiśmie
Type
artykuł w czasopiśmie wyróżnionym w JCR
Language
angielski
Publication year
2014

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