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Gdańsk University of Technology

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DDQ-mediated synthesis of functionalized unsymmetrical disulfanes

We developed a simple and efficient method for the synthesis of functionalized unsymmetrical disulfanes under mild conditions in good yields. The designed method is based on the reaction of bis(5,5- dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfane with thiols in the presence of 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ). The developedmethod allows the preparation of unsymmetrical disulfanes bearing additional hydroxy, carboxy, or amino functionalities.

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DOI
Digital Object Identifier link open in new tab 10.1039/c5ra04173b
Category
Publikacja w czasopiśmie
Type
artykuł w czasopiśmie wyróżnionym w JCR
Language
angielski
Publication year
2015

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