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Gdańsk University of Technology

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Dipole-driven dynamics for near-threshold electron/positron interactions with pyrimidinic DNA bases: a path to compound formations

Calculations are reported for electron and positron scattering from isolated cytosine and thymine, where the two pyrimidinic single-ring DNA bases, in the gas-phase at energies near the elastic threshold, they reveal the special features of the dipole-driven scattering states. All molecules examined exhibit, in fact, supercritical (>1.67 D) permanent dipoles which can therefore also support, below threshold, excited bound compound states (M·e− and M·e+) classified as dipole-bound states. The possible paths for going from above to below the energy threshold to form whole, unfragmented bound complexes are discussed for both leptonic projectiles.

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