Self-assembled bi- and polymetallic complexes of CoII, NiII, ZnII, and CdII were obtained by the reaction of 4,4′-azopyridine (azpy) with metal tri-tert-butoxysilanethiolates (Co, 1; Cd, 2), acetylacetonates (Ni, 3; Zn, 4), and acetates (Cd, 5). All compounds were characterized by single-crystal X-ray structure analysis, elemental analysis, FTIR spectroscopy, and thermogravimetry. Complexes 1, 2 and 4, 5 exhibit diverse structural conformations: 1 is bimetallic, 2 and 4 are 1D coordination polymers, and 5 is a 2D coordination framework formed from bimetallic units. The obtained complexes contain metal atoms bridged by a molecule of azpy. The luminescent properties of 1–5 were investigated in the solid state.
Authors
- dr hab. inż. Agnieszka Pladzyk link open in new tab ,
- dr hab. inż. Łukasz Ponikiewski link open in new tab ,
- prof. dr hab. inż. Anna Dołęga link open in new tab ,
- Klaudia Słowy link open in new tab ,
- Agata Sokołowska link open in new tab ,
- Katarzyna Dziubińska link open in new tab ,
- Zbigniew Hnatejko
Additional information
- DOI
- Digital Object Identifier link open in new tab 10.1002/asia.201500652
- Category
- Publikacja w czasopiśmie
- Type
- artykuł w czasopiśmie wyróżnionym w JCR
- Language
- angielski
- Publication year
- 2015
