Relative abundances of positively ionized water clusters formed in a low-pressure electrical discharge as function of reduced electric field were obtained by using drift cell and quadrupole mass spectrometer. It was noticed that some clusters say with n = 4 were more abundant than others, at comparable drift conditions. Dissociation energies have been derived from equilibrium conditions for relative clusters abundances. The Hartree-Fock method in 6-311G** molecular-basis set has been applied to calculations of binding energies for different structural "families" of clusters. (C) 2003 Elsevier Science Ltd. All rights reserved.
Authors
- T. Wróblewski,
- dr Leszek Ziemczonek link open in new tab ,
- dr Emil Gazda link open in new tab ,
- G.p. Karwasz
Additional information
- DOI
- Digital Object Identifier link open in new tab 10.1016/s0969-806x(03)00307-4
- Category
- Publikacja w czasopiśmie
- Type
- artykuł w czasopiśmie wyróżnionym w JCR
- Language
- angielski
- Publication year
- 2003
