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Gdańsk University of Technology

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High-performance method of carbon nanotubes modification by microwave plasma for thin composite films preparation

In this work we present a simple and efficient method of nitrogen plasma modification of carbon nanotubes (CNTs). The process allows for treatment of the nanotubes in the form of powder with quite a high yield (65 mg of CNTs per hour). The modified carbon nanotubes contain approx. 3.8% of nitrogen, mostly in the pyridinic form. Plasma treated CNTs exhibit better dispersibility in water and higher electric capacitance than pristine CNTs. Modified CNTs are a proper component of novel nanocomposites based on the conducting polymer poly(3,4-ethyleneidoxythiophene. Electrodeposited thin layers of the nanocomposite exhibit improved electrochemical properties (higher capacitance, better stability, lower resistance, faster diffusion) compared to the pure polymer layers.

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