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Gdańsk University of Technology

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Quasirelativistic potential energy curves and transition dipole moments of NaRb

We report on extensive calculations of quasi-relativistic potential energy curves and, for the first time, transition dipole moments including spin-orbit and scalar-relativistic effects of the NaRb molecule. The calculated curves of the 0+, 0-, 1, 2 and 3 molecular states correlate for large internuclear separation with the fourteen lowest atomic energies up to the Na(3s ^2S_{1/2}) + Rb(7s ^2S_{1/2}) atomic limit. Several new features of the potential energy curves have been found.

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DOI
Digital Object Identifier link open in new tab 10.1016/j.chemphys.2017.10.005
Category
Publikacja w czasopiśmie
Type
artykuł w czasopiśmie wyróżnionym w JCR
Language
angielski
Publication year
2018

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