A copper-tartrate, [Cu2(Tart)2(H2O)2]·4H2O, was synthesized at room temperature in aqueous media using copper chloride and D-tartaric acid. The compound crystallizes in the monoclinic system P21 space group and was characterized by infrared spectroscopy, thermogravimetry, X-ray powder diffraction and the results are in good agreement with the single crystal structure. Catalytic properties for allylation of aldehydes were investigated at different solvents, and the best conditions obtained were using a mixture of CH2Cl2:H2O. The copper-tartrate obtained showed good performance as catalyst for different substrates and yields were between 62% and 95%
Authors
- Dr Gilson Da_silva,
- Paulo Menezes,
- Ivani Malvestiti,
- Eduardo H. L. Falcão,
- Severino Alves Junior,
- prof. dr hab. inż. Jarosław Chojnacki link open in new tab ,
- Fausthon F. da Silva
Additional information
- DOI
- Digital Object Identifier link open in new tab 10.1016/j.molstruc.2017.10.096
- Category
- Publikacja w czasopiśmie
- Type
- artykuł w czasopiśmie wyróżnionym w JCR
- Language
- angielski
- Publication year
- 2018
