We describe three previously unreported superconductors, BaPb3, Ba0.89Sr0.11Pb3, and Ba0.5Sr0.5Pb3. These three materials, together with SrPb3, form a distinctive isoelectronic family of intermetallic superconductors based on the stacking of Pb planes, with crystal structures that display a hexagonal to cubic perovskite-like progression, as rarely seen in metals. The superconducting transition temperatures (Tc) are similar for all −2.2 K for BaPb3, 2.7 K for Ba0.89Sr0.11- Pb3, and 2.6 K for Ba0.5Sr0.5Pb3, and the previously reported Tc of SrPb3, ∼2 K, is confirmed. The materials are moderate coupling superconductors, and calculations show that the electronic densities of states at the Fermi energy are primarily contributed by Pb. The observations suggest that the Pb-stacking variation has only a minor effect on the superconductivity.
Authors
- Tai Kong,
- dr inż. Karolina Górnicka link open in new tab ,
- Sylwia Gołąb,
- Bartlomiej Wiendlocha,
- prof. dr hab. inż. Tomasz Klimczuk link open in new tab ,
- Robert J. Cava
Additional information
- DOI
- Digital Object Identifier link open in new tab 10.7566/jpsj.87.074711
- Category
- Publikacja w czasopiśmie
- Type
- artykuł w czasopiśmie wyróżnionym w JCR
- Language
- angielski
- Publication year
- 2018