Functionalized graphene was efficiently prepared through ball-milling of graphite in the presence of dry ice. In this way, oxygen functional groups were introduced into material. The material was further chemically functionalized to produce graphene derivative with phosphonic groups. The obtained materials were characterized by spectroscopic and microscopic methods, along with thermogravimetric analysis. The newly developed material was used as an efficient mercury adsorbent, showing high adsorption efficiency. The adsorption isotherms were fitted using Freundlich and Langmuir models. The adsorption kinetics were fitted with pseudo-first order and pseudo-second order models. Adsorption selectivity was determined in the presence of cadmium ions and nickel ions. The presence of mentioned bivalent ions in the solution did not affect mercury adsorption efficiency.
Authors
- Robert Stanisław Olszewski link open in new tab ,
- Małgorzata Nadolska link open in new tab ,
- dr hab. inż. Marcin Stanisław Łapiński link open in new tab ,
- dr inż. Marta Prześniak-Welenc link open in new tab ,
- dr inż. Bartłomiej Cieślik link open in new tab ,
- dr hab. inż. Kamila Sadowska link open in new tab
Additional information
- DOI
- Digital Object Identifier link open in new tab 10.3390/nano9040485
- Category
- Publikacja w czasopiśmie
- Type
- artykuł w czasopiśmie wyróżnionym w JCR
- Language
- angielski
- Publication year
- 2019