In this work, the fabrication of [Fe(pz)Pt(CN)4] (pz = pyrazine) thin films by means of matrix-assisted pulsed laser evaporation (MAPLE) was investigated. As starting material, a cryogenically cooled suspension of anocrystalline [Fe(pz)Pt- (CN)4] (0.35wt.-%) in a mixture of 1,1-dichloroethane and polyethylene glycol (PEG) was used. Films of a thickness up to 150–200 nm were deposited on Si substrates by laser ablation at λ = 1064 nm of the cryogenically cooled material. PEG impregnated films exhibit a cooperative first-order hysteretic spin crossover behavior around 155 K as detected by Raman spectroscopy. Most interestingly, deposition of a crystalline material was achieved through MAPLE deposition
Authors
- dr hab. inż. Sawczak Mirosław,
- dr hab. Rafał Jendrzejewski link open in new tab ,
- mgr inż. Dominik Maskowicz,
- dr Garcia Yann,
- dr Astha C. Gosh,
- prof. dr hab. inż. Maria Gazda link open in new tab ,
- Jakub Czechowski link open in new tab ,
- prof. Gerard Śliwiński
Additional information
- DOI
- Digital Object Identifier link open in new tab 10.1002/ejic.201900231
- Category
- Publikacja w czasopiśmie
- Type
- artykuły w czasopismach
- Language
- angielski
- Publication year
- 2019
