Publications Repository - Gdańsk University of Technology

In the presented work, for the first time, the metal-modified defective titanium(IV) oxide nanoparticles with well-defined titanium vacancies, was successfully obtained. Introducing platinum and copper nanoparticles (NPs) as surface modifiers of defective d-TiO2 significantly increased the photocatalytic activity in both UV-Vis and Vis light ranges. Moreover, metal NPs deposition on the magnetic core allowed for the effective separation and reuse of the nanometer-sized photocatalyst from the suspension after the treatment process. The obtained Fe3O4@SiO2/d-TiO2-Pt/Cu photocatalysts were characterized by X-ray diffractometry (XRD) and specific surface area (BET) measurements, UV-Vis diffuse reflectance spectroscopy (DR-UV/Vis), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). Further, the mechanism of phenol degradation and the role of four oxidative species (h+, e−, •OH, and •O2−) in the studied photocatalytic process were investigated

Authors

• mgr inż. Zuzanna Bielan link open in new tab ,
• Agnieszka Sulowska link open in new tab ,
• dr inż. Szymon Dudziak link open in new tab ,
• dr hab. inż Siuzdak Katarzyna,
• dr hab. inż. Jacek Ryl link open in new tab ,
• prof. dr hab. inż. Anna Zielińska-Jurek link open in new tab