Spinel oxides with the general formula Mn1.7Cu1.3-xFexO4 (x= 0, 0.1, 0.3, 0.5) were prepared and evaluated in this work for their properties at high temperatures. The effect of partially substituting Cu by Fe has not been studied so far for this group of materials and is thus evaluated in this work. Mn1.7Cu1.3-xFexO4 powders were synthesised by a soft chemistry process and studied in terms of crystallographic phase analysis, electrical conductivity, thermal expansion, and sinterability behaviour. The results show that the Fe content has a significant influence on the phase composition and the resulting properties. Characterisation of the dilatometry and conductivity coupled with XRD phase analysis across a wide temperature range allowed the relations between the materials properties and compositions to be observed. The results indicate that Mn1.7Cu0.8Fe0.5O4 is a promising material for use as a protective coating for interconnects in intermediate temperature Solid Oxide Fuel Cells.
Authors
- mgr inż. Justyna Ignaczak link open in new tab ,
- Yevgeniy Naumovich,
- dr inż. Karolina Górnicka link open in new tab ,
- Jan Jamroz,
- Wojciech Wróbel,
- dr hab. inż. Jakub Karczewski link open in new tab ,
- Ming Chen,
- prof. dr hab. inż. Piotr Jasiński link open in new tab ,
- dr hab. inż. Sebastian Molin link open in new tab
Additional information
- DOI
- Digital Object Identifier link open in new tab 10.1016/j.jeurceramsoc.2020.07.001
- Category
- Publikacja w czasopiśmie
- Type
- artykuły w czasopismach
- Language
- angielski
- Publication year
- 2020
