Mixed-matrix membranes (MMMs) using UiO-66 nanofillers as dispersing inorganic phase and polyetherimide (PEI) as continuous polymeric matrix were synthesized. Different UiO-66 loadings of 10, 20, and 30 wt % were applied. The morphology and UiO-66 dispersion over the prepared MMMs were examined. Gas separation measurements were performed for H2/CO2 gas mixture to evaluate the influence of UiO-66 on the separation yield of resulting membranes. When compared with pristine PEI membranes, MMMs containing metal-organic framework (MOF) nanoparticles revealed superior H2 permeability and H2/CO2 separation factor, e.g., maximum permeability values of 14.6 and 5.5 Barrer were observed for H2 and CO2 at a filler loading of 10 wt % and an applied pressure of 4.0 bar.
Authors
- Muhammad Imad,
- dr Roberto Castro Munoz link open in new tab ,
- Milan Bernauer,
- Violeta Martin,
- Pavel Izak,
- Vlastimil Fíla
Additional information
- DOI
- Digital Object Identifier link open in new tab 10.1002/ceat.202200599
- Category
- Publikacja w czasopiśmie
- Type
- artykuły w czasopismach
- Language
- angielski
- Publication year
- 2023
