We synthesized phosphanylphosphaalkenes (biph)2C=P-P(tBu)2 (2), Ph2CvP-P(NEt2)2 (3), and (biph)2CvP-P(NEt2)2 (4). The diaminophosphanyl derivatives reversibly dimerize head-to-head and react with a ruthenium complex, leading to P–P bond activation and the formation of a bridging phospaalkene complex under mild conditions.
Authors
- dr inż. Aleksandra Ziółkowska link open in new tab ,
- dr inż. Tomasz Kruczyński,
- Gudat Dietrich,
- dr hab. inż. Łukasz Ponikiewski link open in new tab
Additional information
- DOI
- Digital Object Identifier link open in new tab 10.1039/d4dt03012e
- Category
- Publikacja w czasopiśmie
- Type
- artykuły w czasopismach
- Language
- angielski
- Publication year
- 2024
