Repozytorium publikacji - Politechnika Gdańska

Series of the calix[4]arene phosphonic acids with various substituents at the lower rim was synthesized. Complexing properties of these receptors towards methyl esters of six amino acids strongly depended on the calix[4]arene conformation flexibility. The complex formation processes were monitored using 1H NMR spectroscopy (deuterated phosphate buffer at pD 7.3, 22 oC) and association constant values were evaluated. Inherently mobile calix[4]arene molecule 3 occurred in cone conformation in aqueous solution turned out to be more effective in complexation of the basic amino acids methyl esters compared to the rigid 2 and flexible 4. Mixed 1:2 and 2:1 (host-guest) complexes were observed for compound 1 with all amino acids methyl esters.

Autorzy

• Joanna Dziemidowicz link otwiera się w nowej karcie ,
• prof. dr hab. inż. Dariusz Witt link otwiera się w nowej karcie ,
• prof. dr hab. inż. Janusz Rachoń link otwiera się w nowej karcie