Repozytorium publikacji - Politechnika Gdańska

The title chain polymer compound, [GaLi2Br(C3H9OSi)4(C4H8O)2]n, was obtained in the reaction of GaBr3 with Me3SiOLi in toluene/tetrahydrofuran. The GaIII atom, located on a twofold rotation axis, is coordinated by four trimethylsilanolate ligands and has a distorted tetrahedral geometry. The LiI atom is four coordinated by one bridging Br atom located on an inversion centre, two trimethylsilanolate ligands and one tetrahydrofurane molecule in a distorted tetrahedral geometry. The polymeric chains extend along [001]. The tetrahydrofurane molecule is disordered over two positions with site-occupancy factors of 0.57 (2) and 0.43 (2).

Autorzy

• dr hab. inż. Rafał Grubba link otwiera się w nowej karcie ,
• dr hab. Katarzyna Kazimierczuk link otwiera się w nowej karcie ,
• prof. dr hab. inż. Jerzy Pikies link otwiera się w nowej karcie