Repozytorium publikacji - Politechnika Gdańska

This work presents thermal studies of nanocomposites based on the flexible polyurethane (PU) matrix and filled using montmorillonite organically modified with organophosphorus flame retardant compound. Flexible PU nanocomposite foams were prepared in the reaction carried out between reactive alcoholic hydroxyl and isocyanate groups with the ratio of NCO to OH groups equal to 1.05. The amount of an organoclay ranging from 3 to 9 vol% was added to the polyol component of the resin before mixing with isocyanate. The apparent density of PU foams was ranging from 0.066 to 0.077 g cm-1. Thermal properties of the flexible PU nanocomposite foams were investigated by thermogravimetry and dynamical mechanical analysis. Glass transition temperatures (Tg) were defined as maximum peak on tand curve. Thermal decomposition was observed at 310–320 C (calculated from the onset of TG curve). Tensile strength of the PU foams was determined using mechanical test. The microstructure of the nanoparticles and the composites was investigated by X-ray diffraction. Finally, it was confirmed that the thermal and mechanical properties of flexible PU nanocomposite depend on the amount of nanoclay.

Autorzy

• dr hab. inż. Łukasz Piszczyk link otwiera się w nowej karcie ,
• mgr inż. Magdalena Danowska link otwiera się w nowej karcie ,
• dr inż. Anna Mietlarek-Kropidłowska link otwiera się w nowej karcie ,
• Magdalena Szyszka link otwiera się w nowej karcie ,
• dr hab. inż. Michał Strankowski link otwiera się w nowej karcie