Repozytorium publikacji - Politechnika Gdańska

The adiabatic potential energy curves of the ^1Sigma+ and ^1Pi states of the LiH molecule were calculated. They correlate asymptotically to atomic states, such as 2s + 1s, 2p + 1s, 3s + 1s, 3p + 1s, 3d + 1s, 4s + 1s, 4p + 1s and 4d + 1s. A very good agreement was found between our calculated spectroscopic parameters and the experimental ones. The dynamics of the rotational predissociation process of the 1^1Pi state were studied by solving the time-dependent Schrodinger equation. The classical experiment of Velasco [Can. J. Phys., 1957, 35, 1204] on dissociation in the 1^1Pi state is explained for the first time in detail.

Autorzy

• dr inż. Patryk Jasik link otwiera się w nowej karcie ,
• prof. dr hab. Józef Eugeniusz Sienkiewicz link otwiera się w nowej karcie ,
• J. Domsta,
• N. Henriksen