The singlet exciton diffusion lengths are determined by the photoconductivity as well as the luminescence surface quenching technique, in vacuum‐evaporated layers of (4,4′,4″‐tris(N‐(3‐methylphenyl)‐N‐phenylylamino) triphenylamine) (m‐MTDATA), 4,4′,4″‐tris[2‐naphthyl(phenyl)amino] triphenylamine (2TNATA), and N,N′‐diphenyl‐N,N′‐bis(3‐methylphenyl)‐[1,1′‐biphenyl]‐4,4′‐diamine (TPD) which are frequently used for fabrication of electroluminescent and photovoltaic devices. The values are found to be as high as (30 ± 10) nm in 2TNATA and m‐MTDATA, as well as (46 ± 9) nm in TPD films. The corresponding singlet diffusion coefficients of the range between 1 × 10−3 and 1 × 10−2 cm2 s−1, according to a comprehensive study undertaken, are assigned to a sizable electronic coupling induced by strong interactions of intra‐ and inter‐molecular origin in the investigated materials.
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Informacje dodatkowe
- DOI
- Cyfrowy identyfikator dokumentu elektronicznego link otwiera się w nowej karcie 10.1002/pssb.201800043
- Kategoria
- Publikacja w czasopiśmie
- Typ
- artykuł w czasopiśmie wyróżnionym w JCR
- Język
- angielski
- Rok wydania
- 2018