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Electric transport in organic system with planar DBP/F16ZnPc junction on the basis of direct current and small signal admittance spectra analysis

The objective of this work was to determine electric transport in the organic device based on a planar junction of electron donor and electron acceptor materials, namely ITO/MoO3/DBP/F16ZnPc/BCP/Ag. The analysis reported herein was based on direct current-voltage measurements and small-signal admittance spectra in the dark and under illumination. Such analysis may provide information on potential barriers, parasitic resistances and presence of space charge affecting the electric current flow within the device. Therefore, this approach could be applied for determination of physical processes related to electric charge transport within multilayer structures, such as photovoltaic cells or photodetectors. In the case of the investigated system, the parallel parasitic resistance, the resistance of electrodes, and the geometric capacitance of 10 MΩ, 55 Ω, and 1.6 nF respectively were found. It was also shown that the direct current flowing from ITO to Ag was limited by charge carrier injection from electrodes, while in the case of current flowing from Ag to ITO no essential barriers at electrodes were noticed.

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