Repozytorium publikacji - Politechnika Gdańska

The cycloaddition of CO2 to epoxides represents a green efficient method to form bis(cyclic carbonate)s. The main purpose of the work reported in this paper was to examine the effect of the gas flow rate (20, 40, 60 and 100 mL min–1) during carbonation on the conversion yield, chemical structure, rheological behaviour and thermal properties of the prepared compounds. A series of new bis(cyclic carbonate)s was obtained from bio‐based polyether polyol. The syntheses were performed in the absence of toxic solvents and the process did not require the use of elevated pressure. The progressive structural changes and the presence of characteristic chemical groups were monitored by attenuated total reflection Fourier transform infrared spectroscopy. The characterization of the structure by 1H NMR and 13C NMR also confirmed the formation of cyclic carbonate moieties. The non‐Newtonian behaviour and the optimal mathematical model (Herschel–Bulkley) were verified by rheological measurements. The materials obtained could be used as a chemical intermediate to synthesize advanced materials based upon polyurethanes without using isocyanates

Autorzy

• Kamila Błażek link otwiera się w nowej karcie ,
• prof. dr hab. inż. Janusz Datta link otwiera się w nowej karcie ,
• Alicja Cichoracka link otwiera się w nowej karcie