Repozytorium publikacji - Politechnika Gdańska

Metal-organic frames (MOFs) are regarded as excellent candidates for supercapacitors that have attracted much attention because of their diversity, adjustability and porosity. However, both poor structural stability in aqueous alkaline electrolytes and the low electrical conductivity of MOF materials constrain their practical implementation in supercapacitors. In this study, bimetallic CoNi-MOF were synthesized to enhance the electrical conductivity and electrochemical activity of nickel-based MOF, as well as the electrochemical performance of the CoNi-MOF in multiple alkaline electrolytes was investigated. The CoNi-MOF/active carbon device, as-fabricated with a 1 M KOH electrolyte, possesses a high energy density of 35 W h kg−1 with a power density of 1450 W kg−1, exhibiting outstanding cycling stability of 95% over 10,000 cycles. The design of MOF-based electrode materials and the optimization selection of electrolytes pave the way for constructing high-performance supercapacitors.

Autorzy

• Xianyu Chu,
• Fanling Meng,
• Wei Zhang,
• He Yang,
• Xu Zou,
• dr hab. inż. Sebastian Molin link otwiera się w nowej karcie ,
• prof. dr hab. inż. Piotr Jasiński link otwiera się w nowej karcie ,
• Xiangcheng Sun,
• Weitao Zheng