Repozytorium publikacji - Politechnika Gdańska

Three reactions of phosphanylphosphaalkene (1) with nucleophiles were performed to activate the diphosphorus monomer. We observed similar results in the reactions with MeLi and nBuLi, in which the P–P bond is cleavaged and triphosphorus systems [P(Me)2–CH(biph)–CH(biph)–P–(PtBu 2)]- (1a'') and [P(nBu)2–CH(biph)–CH(biph)–P–(PtBu 2)]- (1b''), respectively, are formed depending on the nucleophilic reagent (biph ¼ biphenyl). In the case of tBuLi, the P–P bond remains intact; on the phosphorus atom,only one -tBu group is substituted, and as a result, [(biph)(H)C–P(tBu)–PtBu2]- (1c) is generated as a stable carbanion. We additionally investigated the effect of substitution in the phenyl ring in the course of these reactions by involving two other phosphanylphosphaalkenes (3 and 4). All initial reactions were conducted in tetrahydrofuran (THF) solution at ambient temperature.

Autorzy

• dr inż. Aleksandra Ziółkowska link otwiera się w nowej karcie ,
• mgr inż. Natalia Szynkiewicz link otwiera się w nowej karcie ,
• dr hab. inż. Łukasz Ponikiewski link otwiera się w nowej karcie