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Repozytorium publikacji
Politechniki Gdańskiej

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Application of multicriteria decision analysis to assess the greenness of molecularly imprinted polymers synthesis components

The study applies multicriteria decision analysis (MCDA) to rank the components of molecularly imprinted polymers (MIPs) synthesis according to their greenness. The components are taken from papers that are describing synthesis of MIPs for persistent organic pollutants (POPs) sorbents. Functional monomers (n = 14), target/surrogate molecules (n = 10), porogens (n = 8), cross-linking agents (n = 8) and initiators (n = 4) are described with 10 criteria referring to their safety of application, toxicity, environmental persistence and bioaccumulability. The rankings are performed according to three scenarios, with the application of different weights. The ranking results give a specific guide on the selection of green synthesis components for polybrominated biphenyl ethers (PBDEs) as representatives of POPs, by identification of problematic and recommended chemicals. The results are useful in designing MIP synthesis protocols.

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