Repozytorium publikacji - Politechnika Gdańska

The reaction of iodosylbenzene with >P(O)H type of acids (dialkyl phosphites, secondary phosphine oxides) was studied. The acids of >P(O)H type add to iodosylbenzene to yield intermediate 6 which in the aprotic solvents yields oxidation products, it means >P(O)OH acids and/or anhydride of >P(O)OP(O)< type. On the other hand if the reaction is performed in alcohol as a solvent in the presence of sodium alcoholate >P(O)OR ester is the major product.

Autorzy

• dr hab. Sławomir Makowiec link otwiera się w nowej karcie ,
• prof. dr hab. inż. Janusz Rachoń link otwiera się w nowej karcie