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From weak- to strong-coupling superconductivity in the AlB2-type solid solution SrGa1−xAlxGe with honeycomb layers
- Dorota I Walicka
- Olivier Blacque
- Tomasz Klimczuk
- Fabian O. von Rohr
We report on the structure and the superconducting properties of 9-electron 111 compounds with honeycomb layers, namely SrGaGe, SrAlGe, and the SrGa1−xAlxGe solid solution. By means of single-crystal x-ray diffraction we show that, on one hand, SrGaGe crystallizes into the centrosymmetric P6/mmm space group (a = 4.2555(2) Å, c = 4.7288(2) Å) with statistical disorder in the [GaGe]2− 6 honeycomb layers. On the other hand, we confirm that SrAlGe crystallizes in a non-centrosymmetric space group, namely P6m2 (a = 4.2942(1) Å, c = 4.7200(2) Å) with fully ordered [AlGe]2− 6 honeycomb layers. By using magnetization and specific heat measurements, we show that the superconducting properties of SrGaGe and SrAlGe differ significantly from each other. SrGaGe is a superconductor with a critical temperature of Tc = 2.6 K falling into the weak coupling limit, while SrAlGe has a Tc = 6.7 K and can be classified in the strong coupling limit. By realizing the SrGa1−xAlxGe solid solution, we were able to investigate the transition between the different crystal structures as well as the evolution of the electronic properties. We show that the transition from the weak-to strong-coupling superconductivity in this system is likely associated with the disorder-to-order transition of the honeycomb layer, along with the loss of the inversion center in the crystal structure.
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FRP-based reinforcement coatings of steel with application prospects in ships and offshore structures: a review
- Abu Al Hassan
- Krzysztof Wołoszyk
- Przemysław Krata
Latest research on novel FRP-based anti-corrosion structural coatings (for enhancing structural capacity and strengthening the coating layer) is discussed with application prospects for ships and offshore structures. In the marine environment, structures constantly face corrosion and fatigue cracks. Combining this with high operational and wave loads, it might cause a structural collapse. Recently, polymer composites have been studied for possible reinforcement, especially for steel structures in civil engineering. It is important to assess their effectiveness and review of research on the fatigue, tensile, buckling, and debonding properties of fibre-based structural coatings is given and summarised. Most research focused on carbon fibre reinforced composites. Resins matrices other than epoxy, behaviour on corroded steel, ply orientation, and pre-stress level are still untapped adequately. Similarly, another types of fibres than carbon and their hybrids are still insufficiently examined. Although such research direction is promising, the need for future research is highlighted and given in detail.
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Fuel price, income and road safety as determinants of the level of the population’s economic well-being in Poland
- Oleksandr Melnychenko
- Tetiana Osadcha
- Tetyana Kalna-Dubinyuk
The opportunity to travel is one of the most favorite human activities, given that on a trip a person gets new knowledge, impressions and positive emotions. Recreational trips occupy a prominent place in the concept of the economics of happiness, and the study of factors that influence decision-making regarding travel is important for forecasting the number of tourists, infrastructure development, income and expenses of businesses and authorities. Using the panel data representative of Poland, the authors concluded that the price of fuel and the level of actual income are not key factors for travelers. At the same time, the proposed model gives an error of forecasting the number of tourists less than 1% on average for the entire period of research of monthly data from January 2014 to May 2022 on the cost of fuel at gas stations, the level of population’s income, the level of inflation and the level of drivers’ decency on the road. The obtained data can be used to calculate estimates of the flow of tourists, the level of welfare and happiness of the society.
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Fully Tunable Analog Biquadratic Filter for Low-Power Auditory Signal Processing in CMOS Technologies
- Waldemar Jendernalik
- Jacek Jakusz
A novel Gm-C structure of a second-order continuous-time filter is proposed that allows for the independent control of the filter’s natural frequency (ω0) and quality factor (Q). The structure consists of two capacitors and four transconductors. Two transconductors together with the capacitors form a lossless second-order circuit with tunable ω0. The other two transconductors form a variable gain amplifier (VGA) which realizes an adjustable loss and thereby adjustable Q. The proposed solution can be used to implement low-voltage and low-power tunable front-end filter banks for fully integrated CMOS cochlear implants and edge intelligence accelerators. An example filter bank powered by 0.5 V and consuming 40 nW of power per single filter is designed and simulated using a 180 nm CMOS process. Circuitries for the adaptive control of transistor bias at a reduced supply voltage are proposed. The ω0 and Q control circuitries are also proposed: a delay-locked loop (DLL)-based system for fine ω0 tuning and a binary-weighted current mirror for Q adjustment. The proposed solution allows for the independent regulation of ω0 and Q within the ranges of 0.25–8 kHz and 1–14, respectively, with a relative tolerance of up to 5% across a filter bank.
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Functional similarities and differences among subunits of the nascent polypeptide-associated complex (NAC) of Saccharomyces cerevisiae
- Brenda A. Schilke
- Thomas Ziegelhoffer
- Przemysław Domański
- Jaroslaw Marszalek
- Bartlomiej Tomiczek
- Elizabeth Craig
Protein factors bind ribosomes near the tunnel exit, facilitating protein trafficking and folding. In eukaryotes, the heterodimeric nascent polypeptide-associated complex (NAC) is the most abundant - equimolar to ribosomes. Saccharomyces cerevisiae has a minor β-type subunit (Nacβ2) in addition to abundant Nacβ1, and therefore two NAC heterodimers, α/β1 and α/β12. The additional beta NAC gene arose at the time of the whole genome duplication that occurred in the S. cerevisiae lineage. Nacβ2 has been implicated in regulating the fate of mRNA encoding ribosomal protein Rpl4 during translation via its interaction with the Caf130 subunit of the regulatory CCR4-Not complex. We found that Nacβ2 residues just C-terminal to the globular domain are required for its interaction with Caf130 and its negative effect on growth of cells lacking Acl4, the specialized chaperone for Rpl4. Substitution of these Nacβ2 residues at homologous positions in Nacβ1 results in a chimeric protein that interacts with Caf130 and slows the growth of ∆acl4 cells lacking Nacβ2. Furthermore, alteration of residues in the N-terminus of Nacβ2 or chimeric Nacβ1 previously shown to affect ribosome binding overcomes the growth defect of ∆acl4. Our results are consistent with a model in which Nacβ2’s ribosome association per se, or its precise positioning, is necessary for productive recruitment of CCR4-Not via its interaction with the Caf130 subunit to drive Rpl4 mRNA degradation.
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Functionalized Polyolefins Produced by Post-Metallocenes; High Added Value Materials, but Can They Be Produced Efficiently?
- Wojciech Szot
- Debashis Chakraborty
- Miloud Bouyahyi
- Lidia Jasińska-Walc
- Rob Duchateau
Randomly functionalized polyolefins produced by catalysis have received increasing attention owing to their welldefined molecular structures, uniform distribution, and variety in types of functionalities. Herein, we investigate the scalability of the production of hydroxyl-functionalized propylene copolymers via a high temperature solution polymerization process using aluminum trialkyls as passivating agents. Initially, we evaluated the impact of (i) the type of passivating agent (triethylaluminum versus triisobutylaluminum) and (ii) the distance between the hydroxyl and olefin functionality within the functionalized comonomer on the catalytic activity and the functional comonomer incorporation efficiency. Both the functional comonomer’s chain length and the type of trialkylaluminum passivating agent have a profound effect on the incorporation efficiency. Subsequently, deeper insight into the origin of the catalyst poisoning by trialkylaluminum-passivated hydroxyl-functionalized comonomers reveals that catalyst deactivation solely happens after incorporation of the functional comonomer and not by coordination of the oxygen of the functional comonomers present in the reaction system. During recycling of dialkylaluminum alkenolates by means of distillation, the occurrence of carbo- and/or hydroalumination side reactions were noticed, triggered by the presence of dialkylaluminum hydrides formed by thermolysis of excess aluminum trialkyls. Exchanging aluminum trialkyls by dialkylaluminum alkoxides as scavengers solved this problem. Modeling studies revealed the impact of the higher nuclearity of trialkylaluminum-passivated hydroxyl-functionalized comonomers on their incorporation efficiency. Addition of a saturated alcohol significantly improved the incorporation efficiency of the functional comonomer, thus bringing the scalability (i.e., enhance the productivity and cost-efficiency) of the copolymerization process a step closer.
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Fungal L-Methionine Biosynthesis Pathway Enzymes and Their Applications in Various Scientific and Commercial Fields
- Kamila Rząd
- Aleksandra Kuplińska
- Iwona Gabriel
L-methionine (L-Met) is one of the nine proteinogenic amino acids essential for humans since, in human cells, there are no complete pathways for its biosynthesis from simple precursors. L-Met plays a crucial role in cellular function as it is required for proper protein synthesis, acting as an initiator. Additionally, this amino acid participates in various metabolic processes and serves as a precursor for the synthesis of S-adenosylmethionine (AdoMet), which is involved in the methylation of DNA molecules and phospholipids, as well as in maintaining genome stability. Due to its importance, fungal L-methionine biosynthesis pathway enzymes are being intensively studied. This review presents the current state of the art in terms of their cellular function, usefulness as molecular markers, antifungal targets, or industrial approaches.
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Future opportunities for products derived from black soldier fly (BSF) treatment as animal feed and fertilizer - A systematic review
- Shahida Anusha Siddiqui
- Ankush Subhash Gadge
- Muzaffar Hasan
- Teguh Rahayu
- Sergey Nikolaevich Povetkin
- Ito Fernando
- Roberto Castro Munoz
The pursuit of novel food products with good nutritional value for both direct and indirect human consumption is crucial. Given the nutritional benefits of insects and the sustainability of this sort of farming, using them as food for farmed animals is a promising alternative. In this regard, the black soldier fly (Hermetia illucens) is most capable of efficiently converting a wide variety of organic materials, from food waste to manure, into insect biomass generating value and closing nutrient loops as they reduce pollution and costs. Their larvae have 29% fat and 42% crude protein, yet they have more saturated fats than most insects. They don't concentrate hazards such as mycotoxins or insecticides. Although rapid development is expected, insects remain underutilized in the animal feed industry mainly due to technical, financial, and regulatory barriers. The social stigmas and legal prohibitions against eating organisms that eat waste are added to extant taboos facing insect consumption. Bridging the knowledge gap is crucial to bring together stakeholders and to better understand the opportunities and challenges of this novel industry, so as to develop guidelines on producing insects on an industrial scale to facilitate the wider use of BSF products as animal feed, and fertilizer.
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Fuzzy logic-supported building design for low-energy consumption in urban environments
- Munusamy Arun
- Cristina Efremov
- Van Bac Nguyen
- Debabrata Barik
- Prabhakar Sharma
- Bhaskor Jyoti Bora
- Jerzy Kowalski
- Huu Cuong Le
- Thanh Hai Truong
- Dao Nam Cao
Climate, building materials, occupancy patterns, and HVAC (heating, ventilation, and air conditioning) systems all interact in complex ways, making it difficult to design low-energy buildings. Thus, innovative architectural and engineering design strategies are required to meet the worldwide need to decrease building energy usage. To improve the calculation of energy consumption of buildings, this work introduces the FCR-BCS (fuzzy clustering rule-based building control systems), which integrates fuzzy logic concepts into computational simulations. FCR-BCS can contemplate real-world uncertainties and fluctuations using linguistic factors and approximate reasoning for more precise and trustworthy results in energy-efficient building design. This method's significance rests in its potential to significantly reduce energy use, advance sustainability, and improve urban residents' quality of life; architects and engineers can thus employ FCR-BCS to enhance the efficiency of HVAC systems and insulation. The outcomes of FCR-BCS simulation assessments show that it is capable of making buildings more energy efficient. The experimental outcomes demonstrate that the suggested model increases the sensitivity analysis by 99.4 %, energy efficiency analysis by 99.8 %, occupancy patterns analysis by 97.5 %, temperature profile analysis by 98.8 %, and energy consumption analysis by 99.6 % compared to other existing models.
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Game theory-based virtual machine migration for energy sustainability in cloud data centers
- Francisco Javier Maldonado-Carrascosa
- Sebastián García-Galán
- Manuel Valverde-Ibáñez
- Tomasz Marciniak
- Małgorzata Szczerska
- Nicolás Ruiz-Reyes
As the demand for cloud computing services increases, optimizing resource allocation and energy consumption has become a key factor in achieving sustainability in cloud environments. This paper presents a novel approach to address these challenges through an optimized virtual machine (VM) migration strategy that employs a game-theoretic approach based on particle swarm optimization (PSO) (PSO-GTA). The proposed approach leverages the collaborative and competitive dynamics of Game Theory to minimize energy consumption while using renewable energy. In this context, the game is represented by the swarm, where each player, embodied by particles, carries both competitive and cooperative elements essential to shape the collective behavior of the swarm. PSO is integrated to refine migration decisions, improving global convergence and optimizing the allocation of VMs to hosts. Through extensive simulations and performance evaluations, the proposed approach demonstrates significant improvements in resource utilization and energy efficiency, promoting sustainability in cloud computing environments. This research contributes to the development of environmentally friendly cloud computing systems, thus ensuring the delivery of energy-efficient cloud computing. The results demonstrate that the proposed approach outperforms fuzzy and genetic methods in terms of renewable energy usage. The PSO-GTA algorithm consistently outperforms Q-Learning, Pittsburgh and KASIA across three simulation scenarios with varying cloudlet dynamics, showcasing its efficiency and adaptability, and yielding improvements ranging from 0.68% to 5.32% over baseline results in nine simulations.
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"Gdańskie panoramy z różnych perspektyw’ w ramach cyklu ‘Dojrzały smak przygody’, edycja XX dla Centrum Informacji i Edukacji Ekologicznej, wycieczka edukacyjna
- Agnieszka Kurkowska
Wycieczka prowadziła trasą: Gdańsk Żółty Wiadukt, Grodzisko, Biskupia Górka, Bastion Żubr, Kamienna Śluza, Długi Targ - IKM. Celem była prezentacja widoków panoramicznych z wyjaśnieniem historii ukształtowania i ufortyfikowania miasta. Wskazano współczesne modyfikacje i zwrócono uwagę na zagrożenia w niedbałym planowaniu krajobrazu miasta.
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Gelatin-chitosan interactions in edible films and coatings doped with plant extracts for biopreservation of fresh tuna fish products: A review
- Don Hettiarachchige Udana Eranda
- Manat Chaijan
- Worawan Panpipat
- Supatra Karnjanapratum
- Miguel A. Cerqueira
- Roberto Castro Munoz
The preservation of tuna fish products, which are extremely perishable seafood items, is a substantial challenge due to their instantaneous spoilage caused by microbial development and oxidative degradation. The current review explores the potential of employing chitosan-gelatin-based edible films and coatings, which are enriched with plant extracts, as a sustainable method to prolong the shelf life of tuna fish products. The article provides a comprehensive overview of the physicochemical properties of chitosan and gelatin, emphasizing the molecular interactions that underpin the formation and functionality of these biopolymer-based films and coatings. The synergistic effects of combining chitosan and gelatin are explored, particularly in terms of improving the mechanical strength, barrier properties, and bioactivity of the films. Furthermore, the application of botanical extracts, which include high levels of antioxidants and antibacterial compounds, is being investigated in terms of their capacity to augment the protective characteristics of the films. The study also emphasizes current advancements in utilizing these composite films and coatings for tuna fish products, with a specific focus on their effectiveness in preventing microbiological spoilage, decreasing lipid oxidation, and maintaining sensory qualities throughout storage. Moreover, the current investigation explores the molecular interactions associated with chitosan-gelatin packaging systems enriched with plant extracts, offering valuable insights for improving the design of edible films and coatings and suggesting future research directions to enhance their effectiveness in seafood preservation. Ultimately, the review underscores the potential of chitosan-gelatin-based films and coatings as a promising, eco-friendly alternative to conventional packaging methods, contributing to the sustainability of the seafood industry.
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Gender as a Moderator of the Double Bias of Mistakes – Knowledge Culture and Knowledge Sharing Effects
- Wioleta Kucharska
- Aleksandra Kopytko
There is no learning without mistakes. The essence of the double bias of mistakes is the contradiction between an often-declared positive attitude towards learning from mistakes, and negative experiences when mistakes occur. Financial and personal consequences, shame, and blame force desperate employees to hide their mistakes. These adverse outcomes are doubled in organizations by the common belief that managers never make mistakes, which makes the contradiction even more harmful. Double bias affected leaders select only easy tasks to secure their positions, and those who want to be promoted hide their mistakes to maintain the image of a “perfect employee.” Avoiding the risk of failure is generally not wrong as long as doing so does not block organizational growth. It has been proven that the double bias of mistakes can present a severe hurdle for organizational learning and collective intelligence building. This study explores whether the double bias of mistakes is gender-related and how it affects tacit and explicit knowledge sharing. To do so, it is based on a sample of 183 Polish knowledge workers affected by the double bias of mistakes. The analysis method was ordinary least squares regression, which was conducted with SPSS PROCESS software. Results show that the double bias of mistakes generally causes more problems for female specialists than male specialists and more for male managers than female managers. Regarding managers, male managers probably tend to focus more on control at work. In contrast, women focus on supporting learning (they accept mistakes as a source of knowledge and share knowledge gained from them). Considering current challenges relating to collective intelligence building, women seem to have the potential to be better mentors and, probably, better leaders than men. Such formulated conclusions are based on indirect inferences, so further research is necessary.
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GENDER INEQUALITY IN THE LABOUR MARKET IN KAZAKHSTAN AND UZBEKISTAN
- Krystyna Gomółka
The aim of the following article is to present gender inequality in the labour market in Kazakhstan and Uzbekistan. Gender inequality was researched by analyzing documents providing rights for women and men in Kazakhstan and Uzbekistan. The author presented the unequal treatment of women in the labour market by examining the causes of the level of employment of women and men - contract workers, higher unemployment among women, and finally by the lower remuneration offered to women workers in both countries. The research was conducted on the basis of the analysis of statistical data available on the websites of the Kazakh and Uzbek statistical offices.
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Generalized measurements on qubits in quantum randomness certification and expansion
- Piotr Mironowicz
- Marcus Gruenfeld
- Mohamed Bourennane
Quantum mechanics has greatly impacted our understanding of microscopic nature. One of the key concepts of this theory is generalized measurements, which have proven useful in various quantum information processing tasks. However, despite their significance, they have not yet been shown empirically to provide an advantage in quantum randomness certification and expansion protocols. This investigation explores scenarios where generalized measurements can yield more than 1 bit of certified randomness with a single-qubit system measurement on untrusted devices and against a quantum adversary. We compare the robustness of several protocols to exhibit the advantage of exploiting generalized measurements. In our analysis of experimental data, we were able to obtain 1.21 bits of min-entropy from a measurement taken on one qubit of an entangled state. We also obtained 1.07 bits of min-entropy from an experiment with quantum state preparation and generalized measurement on a single qubit. We also provide finite data analysis for a protocol using generalized measurements and the Entropy Accumulation Theorem. Our exploration demonstrates the potential of generalized measurements to improve the certification of quantum sources of randomness and enhance the security of quantum cryptographic protocols and other areas of quantum information.
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Genetic variations as predictors of dispositional and dyadic empathy - a couple study
- Maria Kaźmierczak
- Magda Rybicka
- Paweł Syty
Biological drivers of empathy have been explored in an interdisciplinary manner for decades. Research that merges the psychological and genetic perspectives of empathy has recently gained interest, and more complex designs and analyses are needed. Empathy is a multidimensional construct that might be regarded both dispositionally (as a personality trait) and contextually (experienced and/or expressed in a particular relationship/situation). This study analyzed genetic variations associated with genes encoding oxytocin, arginine vasopressin, and receptors that regulate their secretion as predictors of the empathic dimensions of emotional (empathic concern and personal distress) and cognitive (perspective taking) dyadic factors of partners in heterosexual intimate relationships. Machine learning methods to capture both linear and nonlinear relationships between SNPs, RS1 and RS2 repeat polymorphisms and dimensions of empathy in couples were employed. A total of 442 individuals (221 couples) participated in this study. Empathy was measured by the Polish version of the Interpersonal Reactivity Index and the Interpersonal Reactivity Index for Couples. The MassARRAY® 4 instrument, which combines mass spectrometry with endpoint PCR, was used for genotyping all 14 genetic variations. Microsatellite fragment analysis was performed by denaturing polyacrylamide gel electrophoresis. The results confirmed the significance of certain genetic alterations linked to oxytocin, vasopressin, serotonin and estrogen for dispositional and dyadic empathy (mainly rs1884051, rs6311, RS1, rs4686302, and rs1042778) in couples. The effects were stronger for the prediction of emotional and dyadic empathy than for perspective taking. Separate analyses for women and men indicated different predictive effects of genes for empathy (for example, effects of rs53576 were indicated only in women), which are also experienced and expressed in couples. Different dimensions of empathy should be included when the genetic predictors of empathy are examined.
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Geometric working volume of a satellite positive displacement machine
- Paweł Śliwiński
This article describes a method for determining the geometric working volume of satellite positive displacement machines (pump and motor). The working mechanism of these machines is satellite mechanism consisting of two non-circular gears (rotor and curvature) and circular gears (satellites). Two variants of the satellite mechanism are presented. In the first mechanism, the rolling line of the rotor is a sinusoid "wrapped" around a circle. In the second mechanism, the rolling line of the rotor is a double sinusoid "wrapped" around a circle. A method for calculating the area of the working chamber as a function of the rotor rotation angle is presented, based on mathematical formulae of the rotor, the curvature and the satellite rolling lines. It has been shown that the second variant of the satellite mechanism is advantageously characterised by a larger difference between the maximum area of the working chamber and the minimum area of this chamber. New mathematical formulas have been proposed to calculate the area of the working chamber for any angle of rotation of the shaft (rotor) based on the maximum and minimum values of the area of this chamber. It was thus confirmed that the geometric working volume depends on the maximum and minimum area of a working chamber and on the height of the satellite mechanism. The analyses of the area of the working chamber were carried out both for the mechanism without gears (the area delimited by the rolling lines of the elements of the mechanism) and for the real mechanism with gears. Differences in the values of these fields were also detected.
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GEOSYSTEMY W BUDOWNICTWIE MORSKIM
- Angelika Duszyńska
- Małgorzata Frączkowska
Budowa i rodzaje geosystemów. Przykłady zastosowań. Aspekty środowiskowe i ekonomiczne.
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Geotechnical Analysis and Stability Assessment of a Landslide Event in Gera Woreda, Ethiopia
- Mulatu Tamiru
- Worku Firomsa Kabeta
- Damtew Tsige
- Hashim Ware
- Zeberga Tenaye
This study investigates the geotechnical factors influencing a recent landslide event in Gera Woreda, Ethiopia. The primary objective was to identify the soil properties contributing to landslide occurrence and understand the triggering mechanisms. Field investigations, soil sampling from both affected and unaffected areas, and subsequent laboratory characterization were conducted. The analysis revealed a dominance of fine-grained soils, such as clay and silt, which are susceptible to weakening upon saturation, thereby increasing landslide susceptibility. Rainfall is identified as the primary trigger for the landslide. Numerical stability assessments using the Limit Equilibrium Method (software, SlideTM) and the Finite Element Method (software, PLAXISVR) were performed to assess the stability of the slopes. The stability analysis revealed a notable decrease in the factor of safety (FS) under rising groundwater levels. For example, the FS for Slope 1 decreased from 1.42 under dry conditions to 0.73 at a 2 m groundwater depth. Similarly, Slope 2’s FS decreased from 2.06 to 1.18 under similar conditions. These results emphasize that rainfall is the primary trigger for landslides in the area. To address this, the study proposes surface drainage systems and the planting of Vetiver grass to improve slope stability. These findings provide critical insights for developing proactive mitigation strategies to protect local communities and infrastructure from landslide hazards.
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Glacial Landform Classification with Vision Transformer and Digital Elevation Model
- Paweł Nadachowski
- Zbigniew Łubniewski
- Jarosław Tęgowski
Classification of glacial landforms is a task in geomorphology that has not been widely explored with deep neural network methods. This study uses Vision Transformer (ViT) architecture to classify glacial landforms using Digital Elevation Model (DEM) in three study sites: Elise Glacier in Svalbard, Norway; Gardno-Leba Plain and Lubawa Upland in Poland. In datasets each of those sites has different DEM resolutions and terrain types which includes end moraines, hummocky moraines, kettle holes, outwash/glaciolacustrine plains, till plains and valleys. The results of the classification show that ViT architecture is a suitable method for this type of task and can achieve up to 97.5% of accuracy. The classification process described in this study can be reproducible and applied to other terrain types around the world.